Showing posts with label snowflakes. Show all posts
Showing posts with label snowflakes. Show all posts

Sunday, 14 March 2010

The Caltech Snowflake Site

thumbnail link image to CalTech's snowflake site, www.snowcrystals.com
While I was finishing off yesterday's snowflake post, I came across Caltech's excellent snowflake site at www.snowcrystals.com (Kenneth G. Libbrecht).

Lots of photos, lots of useful information. Caltech even have their own snowflake creation machine, that, instead of electrostatically levitating the snowflakes as they grow, or using a vertical blower, applies an electric field to grow narrow ice-spikes, and then lets the snowflakes form at the spikes' tips (which means that the central mount is probaby rigidly aligned to the resulting flake with atomic precision, and doesn't seem to affect the growing process).

If you're in the UK, and you've mocked train companies for blaming their electrical locomotive failures on "the wrong kind of snow", well, it turns out that snow crystallisation has a slightly crazy dependency on both temperature and airborne water content, forming a range of very different shapes, from the classic branched hexagon "christmas card" forms, to hexagonal plates or long hexagonal tubes (snowflake chart).

The CalTech site explains the wide variety of snowflake forms by this temperature-dependence: the idea being that snowflakes form symmetrically because the conditions across the flake are the same at any given time, and that the extreme variety of shapes is a function of the varying environmental conditions that the whole snowflake experiences as it falls through different regions of sky. It might go through a "spiky dendrite" phase, then change temperature and start trying to grow plates, and then go back to "dendrite" mode, and the exact amount of time spent in these different phases then dictates the shape that emerges.

If the identical patterning of the arms is purely a result of the identical (varying) growing conditions across the whole flake, then we don't require any additional mechanism for regulating symmetry. In that case, we'll expect individual snowflakes to accumulate diverging asymmetries as they grow, due to gradients of temperature or water availability or light or airflow across the flake. This'd seem to make the formation of extremely regular crystals a bit unlikely.
But the CalTech site argues that actually, most natural snowflakes are pretty irregular, and that people generally overestimate the degree of symmetry because the artsy folks who photograph them (presumably including CalTech!) give a misleading impression by carefully selecting out the "best" (most regular) flakes to photograph and publish.

That explanation seems to be a bit at odds with the current suggestion of how triangular snowflakes form, though: if triangular snowflakes grow because of airflow over the flake creating an asymmetrical growing environment, breaking the hex pattern, then if there wasn't an additional internal regulating symmetry-mechanism, there'd be no obvious reason why the resulting aerodynamically-disfigured flake should have 120-degee rotational symmetry. Airflow and a moisture gradient flowing across the flake in one direction might allows a bilateral left-right symmetry for the two sides of the flake that are experiencing the same growing conditions ... it doesn't explain why the conditions at the leading point of the falling tri-flake (falling point-first) should be identical to that at the two trailing side-points, or why points on the sides of those two trailing spurs points should be equivalent, when the airflow is hitting them at different angles. If triangular flakes are due to sideways airflow, then it means that the flake seems to be fighting to retain some sort of symmetry despite significant asymmetrical disruptive forces that ought to be destroying it. That'd increase the odds of there being a significant internal symmetry mechanism in play.

Of course, it may be that our explanation of triangular snowflakes is simply wrong, that airflow isn't disrupting the hex pattern, and that instead chemical contamination (or some other factor) is causing the alternative triangular crystal structure. But that'd still mean that something in our current understanding of snowflakes is wrong or incomplete. Even if yesterday's wacky suggestion about the quantum mirage effect is midguided, we'd still not know why snowflake formation is so sensitive to environmental conditions, or what the (non-aerodynamic) explanation of triangular snowflakes might be.


So again, more research needed.


The Caltech site's debunking of "mysterious" causes of snowflake symmetry is in the "Myths and Nonsense section" at http://www.its.caltech.edu/~atomic/snowcrystals/myths/myths.htm . The page says that there aren't any special forces at work here regulating symmetry, that most snowflakes are asymmetrical and "rather ugly", and that the published examples (including the ones on the site) are atypical, because "not many people are interested in looking at the irregular ones". In other words, if you look through the published work, you get a misleading impression due to publication bias. Well, yes ... quite possibly. But since the idea of what counts as "significant" symmetry might be a bit subjective,and since the datasets aren't available for us to look at, it's difficult to take this as a definitive answer until there's been actual experimental testing done.

Water is wierd stuff, and it keeps catching us out. I remember when people used to debunk ice spikes as an obvious example of psudoscience, and now those are understood, studied, and have their own page on the CalTech site. A lot of "crazy" ideas about water do turn out to be just as dumb as they first appear, but a few turn out to be correct. The trouble is, it's not always immediately obvious which are which.

Saturday, 13 March 2010

Snowflake Engineering, Quantum Mirages and Matter-Replicators

Julia Set
One of the most impressive things about snowflakes is that we still don't really understand how they work.

We understand how conventional crystals grow – normal crystals assemble into large, faceted, regular-looking forms because the flat facets attract new atoms more weakly than the rougher, "uncompleted" parts of the structure, which provide more friendly neighbours for a new atom to bond with. So if you have an "incomplete" conventional crystal, it'll preferentially attract atoms to the sites needed to fill in the gaps, to produce a nice large-faceted shape that tries to maximise the size of its facets, as far as it can bearing in mind the original random initial distribution of seed crystals.

But snowflakes do something different. Their range of forms makes their growth appears pretty chaotic, but they also manage to be deeply symmetrical. It'd seem that the point of greatest attraction on a region of snowflake doesn't just depend on the atoms that are nearby, but also on the arrangement of atoms on a completely different part of the crystal, which might be some way away, and facing in a different direction, on a different spur. The sixfold symmetry of a snowflake suggests that when you add an atom to the point of one of the six spurs, the other five points become more attractive ... add an atom to the side of a spur, and we're dealing with twelve separate sites (twenty-four if the atom is off the plane). Add an atom to a side-branch, and a copy of the electrical-field image of that single atom is transmitted and reflected and multiplied and refocused at potentially tens of corresponding sites on the crystal surface. And that's for every atom in the crystal.

This would be beyond fibre-optics, and beyond conventional holography. It'd be multi-focus holography, and the holographically-controlled assembly of matter at atomic scales to match a source pattern – making multiple copies without destroying the original. It'd be using holographic projection to assemble multiple macroscopic structures that are atom-perfect copies of an original. And that idea should make the hairs on the back of your neck start to stand up.

The closest thing I've seen in print to this is the quantum mirage effect described in Nature, 3 Feb 2000. Researchers assembled an elliptical quantum corral of atoms on a substrate, and placed another atom at one of the ellipse's two focal points. They then examined the second focal point, and found that the atom's external field properties seemed to be projected and refocused at the second point, to give a partial "ghost" of the source atom [*][*][*]. You could interact with the ghost even though it wasn't there. Presumably your actions on the "ghost particle" copy would be transmitted back to the source, which'd be recreating the ghost behaviour by a process of electrical ventriloquism, using the elliptical reflecting wall to "throw" its voice to the ghost location.

Something similar may be happening in a perfectly-symmetrical monocrystalline snowflake as it grows. Maybe the crystal's regular structure just happens to not just split the image of the atom into multiples, but refocus them with phase coherence at all the key symmetry points. Maybe we could try adding a few metal atoms to one part of a snowflake crystal and seeing if matching atoms are preferentially attracted to the other corresponding sites.



A possible clue is the phenomenon of triangular-symmetry snowflakes.
It's been suggested that these form in nature when an asymmetrical snowflake falls corner-first, with the airflow disrupting regular hexagonal crystal formation (see also Wired). But since the remaining triangular symmetry is still so strong, this hints that perhaps the strongest linkage between crystal sites is in triples, with a secondary slightly weaker triplet attraction producing the hex.

Okay, so I suppose there might be problems in attempting to use giant snowflake crystals as matter-photocopiers ... for snowflake formation, every copied pattern forms an extension of the crystal, if you use the crystal to try to copy other things, then the "irregular" matter being copied is liable to disrupt of the focusing. You might only be able to copy layers an atom or two thick (at least, to start with).

But a giant atom-perfect monocrystalline snowflake would be an awfully fun thing to play with if you had a chip-fabrication lab with goodies like force-sensing tunnelling microscopes.

And to me, that was the one thing that could have justified building the International Space Station. The ability to build a giant, heavy-duty zero-gravity snowflake, hopefully one big and chunky enough to withstand eventually being brought back to Earth immersed in liquid helium for further study (what does Bose-Einstein condensate do when it's in in contact with a hex crystal?). That had to be worth a few billion in research money, and would have given the public something pretty to look at when it came time to tell them what the money had bought. We haven't done it yet, but maybe ...